全液相高温调剖剂的研制

针对汽驱开发试验中出现的汽窜、油层受效不均等问题,研制出一种全液相高温调剖剂,10 g堵剂沉淀量达到1.8 g,无机凝胶强度达到5 MPa/m,封堵率在55％ ～90％间可调,耐温达到350℃,经现场调剖试验后,措施井的注汽压力提高1.7 MPa,吸汽剖面改善明显,调剖效果显著,提高了汽驱的注汽利用率和采收率.     

N-苄氧羰基甘氨酰-L-脯氨酸与4'-去甲基表鬼臼毒素的拼接合成及其抗肿瘤活性评价

以4'-去甲基表鬼臼毒素和N-苄氧羰基甘氨酰-L-脯氨酸为原料,通过酯化反应首次得到两种不同构型的拼接产物(3a、3b),其结构经1HNMR、13C NMR和ESI-MS确认.利用MTT法考察化合物3a、3b对HepG2、THP-1、Hela、MCF-7细胞的抑制活性.结果表明,化合物3a、3b对四种细胞都具有抑制作用,以化合物3b对THP-1细胞的作用最突出,其抑制强度是依托泊苷的16.5倍.     

Studies on waterline corrosion processes and corrosion product characteristics of carbon steel in 3.5 wt% NaCl solution

The waterline corrosion behaviors of carbon steel partially immersed in a 3.5 wt% NaCl solution were investigated using the wire beam electrode technique, and the effects of corrosion products on the processes of waterline corrosion were analyzed. The results demonstrated that the initial stage and development stage of waterline corrosion were mainly controlled by the concentration and diffusion of dissolved oxygen, respectively, and the deceleration stage of waterline corrosion was mainly affected by corrosion products. The main component of the yellow corrosion products was γ-FeOOH, and γ-FeOOH that exhibited a high reduction reactivity could be involved in the cathodic reaction. The black corrosion products were mainly composed of Fe₃O₄ with strong thermodynamic stability and the processes of dissolved oxygen diffusion and ion transports were obviously affected due to the continuous accumulation of Fe₃O₄ on the surface of the electrodes. Polarity reversals were observed on the single electrodes below the waterline, but the reasons for the phenomena were different from each other.     

Fabrication and properties of the superhydrophobic ceria-based composite coating on magnesium alloy

A superhydrophobic ceria-based composite coating is developed to improve anticorrosion properties of AZ61 magnesium alloy, fabricating via chemical conversion method followed by hydrothermal treatment. The cerium conversion coating has a block structure with microcracks. After the hydrothermal treatment, a dense CeO₂ layer, porous CeO₂ nanorods, and stearic absorbing layers are grown stepwise on the conversion coating. And the composite coating is hydrophobic or even superhydrophobic and has almost no microcracks. As the hydrothermal reaction time increases, the water contact angle of the composite coating first increases and then decreases, and it reaches the maximum value of 152° after hydrothermal treatment for 4 h. Both the dense CeO₂ layer and the superhydrophobic stearic absorbing layer can effectively prevent the electrolyte from contacting the substrate; the corrosion current density of the superhydrophobic composite coating is lower than that of the hydrophilic composite coating and the cerium conversion coating, and has the best corrosion resistance.     

含锡废液的安全处理技术研究

论述了两级沉淀法对含锡废液的处理技术,通过实验得到两级沉淀法处置含锡废液的最优条件,实现了含锡废液的安全有效快速处理.     

梁结构振动支承约束反力控制

支承或连接构件对梁结构的动力学性能有至关重要影响,必须保证其在振动过程中不发生破坏或者失效。通过合理设计和布局附加弹性支承可以实现对这些重要连接构件所承受约束反力的控制。应用微分变换法推导含附加支承的梁结构支承约束反力及其对于附加支承位置和刚度的灵敏度表达式,并通过优化设计附加支承位置和刚度实现具有弹性约束端的简支梁结构各支承约束反力的平衡,可提高结构的动力学性能。     

Optical design of the Lyman alpha based beam emission spectroscopy(LAB)diagnostic on the HL-2A tokamak

In this article, we present the optical design of a novel diagnostic on the HL-2 A tokamak, i.e. the20-channel edge Lyman-alpha beam emission spectroscopy, which is a promising solution for edge density turbulence research on tokamaks, as it offers the possibility of density fluctuation measurement with a 3.3 mm spatial resolution while maintains a high temporal resolution of1 μs. The optical path, including the reflective collection optics, the high-dispersion spectrometer, and the linear detector array, is carefully optimized to obtain a good image quality and a high throughput. The maximum root mean square radius of the collection optics is 64 μm.The detected photon flux is estimated to be about 10~(11) photons/s/channel.     

Strong tribocatalytic dye degradation by tungsten bronze Ba4Nd2Fe2Nb8O30

The triboelectric effect has recently demonstrated its great potential in environmental remediation and even new energy applications for triggering a number of catalytic reactions by utilizing trivial mechanical energy. In this study, Ba₄Nd₂Fe₂Nb₈O₃₀ (BNFN) submicron powders were used to degrade organic dyes via the tribocatalytic effect. Under the frictional excitation of three PTFE stirring rods in a 5 mg/L RhB dye solution, BNFN demonstrates a high tribocatalytic degradation efficiency of 97% in 2 h. Hydroxyl radicals (?OH) and superoxide radicals (?O₂－) were also detected during the catalysis process, which proves that triboelectric energy stimulates BNFN to generate electron-hole pairs. The tribocatalysis of tungsten bronze BNFN submicron powders provides a novel and efficient method for the degradation of wastewater dye by utilizing trivial mechanical energy.     

基于归一化水体指数及其阈值自适应算法的水体遥感反演效果分析

归一化水体指数（NDWI）是水体遥感反演的一种重要指标，其阈值及修正直接影响反演结果的精度。基于Landsat-8与GF-1光学多光谱影像，使用归一化水体指数法阈值0（TH₀）、最大类间方差法（OTSU）自适应阈值（TH_otsu）与均值漂移聚类算法（Mean-Shift）自适应阈值（TH_MS）分别对典型正常水体、云雾覆盖水体、富营养化水体、高含泥沙水体进行水体遥感提取与效果分析，结果表明：正常水体以TH₀为阈值提取精度最高，THMS提取精度次之，TH_otsu提取精度最差；而云雾覆盖水体、富营养化水体以及含泥沙水体使用THMS提取精度最高，尤其少量云雾覆盖下的水体，TH_MS具有更明显的优势，TH₀提取精度次之，TH_otsu提取精度最差；对于不同的阈值，Land?sat-8比GF-1总体表现出更高的水体提取精度。Mean-Shift算法应用于NDWI阈值修正与水体遥感反演具有快速、水质适应性强、效果稳定的优势，对尤其是复杂条件下的水体信息遥感反演具有较好的提取效果。